Cover Feature: Ge <sub>32</sub> Co <sub> 9− <i>x</i> </sub> : Creating “Empty” Space by High Pressure (Chem. Eur. J. 16/2023)
نویسندگان
چکیده
Essential structural features of the high-pressure phase Ge32Co9−x: The atomic arrangement is built from a uniquely distorted cubic primitive Ge atoms. Ordered occupation neighboring cubes by Co atoms forms heteroatomic three-core clusters Co3Ge16. These units condense to form two interpenetrating frameworks interlinked covalent Ge−Ge bonds. homopolar germanium bonding creates characteristic six-membered rings. More information can be found in Research Article U. Schwarz and co-workers (DOI: 10.1002/chem.202203955).
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ژورنال
عنوان ژورنال: Chemistry: A European Journal
سال: 2023
ISSN: ['0947-6539', '1521-3765']
DOI: https://doi.org/10.1002/chem.202300591